Selective oxidations of activated alcohols in water at room temperature.

نویسندگان

  • B H Lipshutz
  • M Hageman
  • J C Fennewald
  • R Linstadt
  • E Slack
  • K Voigtritter
چکیده

Allylic and benzylic alcohols can be selectively oxidized to their corresponding aldehydes or ketones in water containing nanoreactors composed of the designer surfactant TPGS-750-M. The oxidation relies on catalytic amounts of CuBr, bpy, and TEMPO, with N-methyl-imidazole; air is the stoichiometric oxidant.

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عنوان ژورنال:
  • Chemical communications

دوره 50 77  شماره 

صفحات  -

تاریخ انتشار 2014